Latest / El futuro fue ayer con Juan Guillermo Martín / Arqueometría, la ciencia de los materiales antiguos
Transcript
- 0:05The future was yesterday? It' s an archaeology podcast where ghosts, conspiracy
- 0:14theories and aliens have no place. I am Juan Guillermo Martín, archaeologist and
- 0:24university professor and with different specialists. It would be scientifically addressing our fascinating past,
- 0:31a past that offers us answers to face the future. Welcome to the
- 0:48podcast The future was yesterday? I' m Jua Guillermo Martín archaeologist. For
- 0:52some years now, in archaeological research we have heard more frequently in terms of
- 0:58neutronic activation analysis, mass spectrometry, scanning electron microscopy, X- ray infringement,
- 1:04among others. It is a set of methods and techniques of physical and
- 1:11chemical analysis applied to archaeological evidence that we know generically as archaeometry, because to
- 1:18talk about such a specialized topic we have a prominent researcher. This is Javier
- 1:23Iñanes, Javier welcome hello, very well found. Juan Guillermo is delighted that
- 1:30you have me here today and that I can build this podcast that is really
- 1:36very interesting, that already has several followers from Spain and that nothing that I
- 1:44hope can shed a little light on what is archaeometry and, in particular,
- 1:49the geometry of ceramics. That' s what Javier will be like. For
- 1:55those who do not know him, Javier Iññez holds a degree in History and
- 1:59a PhD in archaeology from the University of Barcelona. He has been a postdoctoral
- 2:04researcher at the Smithsonian Institution in Washington since the twelfth. He is part of
- 2:08the research teaching team of the University of the Basque Country and postdoctoral researcher of
- 2:15the Ramonica Hall program. He has participated in numerous research projects on archaeology and
- 2:20archaeometry. His main research interest focuses on the study through the archaeometry of trade,
- 2:25cultural exchange and ancient ceramic and glass technology in medieval and modern times in
- 2:31the Peninsurcular North, as well as European colonialism in North Africa and America.
- 2:39He is a member of the archaeometry society, applied to the cultural heritage of
- 2:45the sociedaety Ford Historical Archaeology, and leads the line of research on archaeometry within
- 2:50the Gepack research group of the University of the Basque Country, Bueno Javier.
- 2:54To begin with, we start from the beginning in terms of people looking at
- 3:00what archaeometry is all about, what its origins are, and what materials we
- 3:06can apply to. Well, archaeometry is a branch of archaeology. That is,
- 3:14as we must understand, It is one more tool that brings us knowledge,
- 3:21It contributes to expand the knowledge that we obtain means of archaeology. So,
- 3:28that' s why the issues we raise are not the same. We
- 3:31raise questions in archaeology about the knowledge of the societies of the past and good
- 3:38also of the present, their organizations, cultures, dynamics, adaptations, changes.
- 3:46But of course, what we are really seeing is the cultural aspect of
- 3:49these artifacts. We are in archaeology, we are above all studying the materiality
- 3:54and cultural aspect of that materiality to understand a little how that is. Ancient
- 3:59and good societies, as I said, present as well. So the basic
- 4:02questions are the same. What materials, where they come from, how old
- 4:09they are, how they were used, what they cooked or what they ate.
- 4:15That is, how that material was used or what was eaten in such
- 4:18containers or in such dishes. Then there are some questions that clearly can be
- 4:26answered through cultural characteristics, but there are others that have to take into account
- 4:30the natural side. So, this is where we introduce a concept that,
- 4:38well in origin, was coined by a good Czech archaeologist. And here I
- 4:42hope that our Czech colleagues will forgive me for mistreating the Czech language, because
- 4:46I have no idea and I do not know very well how the Czech archologist
- 4:51who said it is very sorry and zen nutupni that already in the seventies he
- 5:00said that any artifact, any archaeological object has two aspects. One is cultural
- 5:05and the other is natural. And it' s the natural thing because it
- 5:12' s made of material it is. A material can already be a ceramic,
- 5:14a mental, a bone, a plant, everything has, that is,
- 5:19a tree, for example, a wood. Then everything has a verente,
- 5:21also material. So, since it is this natural aspect that we study
- 5:30from archaeometry, then we can study, for example, chemical elements. It
- 5:35' s composed of minerals, which molecules, if it' s something organic,
- 5:43for example, we can study their genetics. Well, it depends on
- 5:46organic material, then nothing. In the end, what archaeometry does is combine
- 5:53that natural knowledge. Let' s say natural sciences with cultural knowledge, human
- 5:59sciences. So, well, a possible definition or a definition one between them,
- 6:06because there are many. This would be the application of techniques and methodologies,
- 6:12of scientific techniques, as they can be, of the natural sciences,
- 6:15of chemistry, of physics, of biology, of geology, to the study
- 6:18of archaeological artifacts and, above all, in an objective that is to answer
- 6:24archaeological questions. Then this would become one of the possible definitions of archaeometry.
- 6:32Here, yes, you want, we can also come in to debate,
- 6:38because it is a sufficient debate, quite interesting that took place above all more
- 6:42years ago and I think it is already quite over. But from time to
- 6:46time it comes that it is the theme of how archaeometry is known in the
- 6:51closachon world. It is often called archological science, of course in Spanish.
- 6:58I believe that, fortunately, we do not define this field as scientific archaeology
- 7:05or as scientifically based archaeology, because, of course, I think you will
- 7:10agree that defining it this way implies that there is a scientific archaeology and an
- 7:15archaeology that is not scientific, is not scientific, and very different is the
- 7:20pseudo archaeology or fantastic archaeology, that that is another matter. But I don
- 7:23' t think I do exact non- scientific archaeology. That is precisely archaeology
- 7:29is based on science, a scientific theoretical cuerpus and is the most scientific of
- 7:40all humanities. Well, then I' m a little clear about continuing with
- 7:46archaeometry. What we studied with archaeometry, since we can study any field from
- 7:55diet, for example, that was eaten in ancient times, that ate more
- 8:03meat, more fish in a region maybe ate. There is a supply of
- 8:07fish that is brought from a more distant area. And well, there are
- 8:13networks of exchange of hierarchies that should be studied in trade, for example.
- 8:20Also many questions about ancient technology. How things were done, how the products
- 8:24were made, the artifacts, what kind of materials they used, what knowledge
- 8:30there was about that production, what recipes. Well, and then, because
- 8:35we can also go further on bioarchaeology issues, as diseases, ancients, human
- 8:41relationships, remote sensing, dating. Here' s the field is vast and
- 8:54then we can do it this way. What archaeometry really is is very broad,
- 8:58because any application of these techniques or of these disciplines for the study and
- 9:09answers of archaeological questions could define it with marquemetry and, in fact, I
- 9:15agree with that definition. The point is that, definitely, the interest,
- 9:22of course, of archaeology will largely be concentrated on those materials that we recover
- 9:28in an archaeological excavation process and a lot of questions arise that even if a
- 9:35few decades we could answer them, as you well said, from a cultural
- 9:39perspective, but that we can now approach them in another way, that is,
- 9:45when we try to get closer to the composition of the raw materials of
- 9:50these different artifacts, for example, ceramics, because they will allow us to
- 9:58know already specific details of where it is produced or at least where the raw
- 10:01materials come from. And that is key to the extent that it allows us
- 10:05to know how human beings relate to their environment, to their environment, or
- 10:09how they establish business connections with other societies, etc. And in that I
- 10:16think archaeometry works in a very very precise way and there is one of these
- 10:22analyses that apply to these materials, which is that of neutron activation. And
- 10:26in that, then, I would assume that it is like one of those
- 10:31pioneering techniques. I would like you to explain to us how the neutron activation
- 10:39works and specifically what information it offers us in the field of archaeology. Yeah,
- 10:45yeah, thanks, that' s what I' m gonna do to
- 10:48you. Neutron really is one of the analytical techniques, or techniques that are
- 10:52used in narcometry, which is one of the most reliable, that is,
- 10:58is the most accurate and most accurate that exists to do elementary chemical quantification analysis.
- 11:07It' s a rather complex technique. That' s right, that
- 11:11' s right, well. It' s based on your showing the irradiates
- 11:15with a neutron flow, so the atoms in that sample some capture, some
- 11:22of those neutrons become unstable. Therefore, radioactive isotopes and these radioactive isotopes are
- 11:31created. What they' re looking for, they' re decaying and they
- 11:39' re looking for more stable configurations and in that process they' re simplifying
- 11:43a lot. What they do is emit a radiation, a gamma radiation energy
- 11:50in this case, and this radiation that is emitted is characteristic of each chemical
- 11:56element, that is, sodium, has a characteristic radiation to some specific wavelengths,
- 12:01iron to others, silicon to others. So, with high- precision
- 12:11detectors, we can actually count how much radiation comes from each element and thus
- 12:20quantify the percentage or quantity of that element in our sample. So it'
- 12:31s pretty interesting. It is also quite interesting the origin of this technique,
- 12:37because you have to look for it in the middle of the 20th century,
- 12:43right with the famous Good, who has long before. But as the final
- 12:48end is the Manhattan project, where the atomic bomb was developed, so,
- 12:52of course, after that, of that achievement I don' t know how
- 13:01to define it. All right, sometimes scientific achievement. Perhaps, human misfortune.
- 13:07We don' t know. Yes, because there was an attempt to
- 13:13look for civil applications, civil applications to that technology and it has many,
- 13:20many, one of them, one of them Well, for example, also
- 13:26in cancer treatments. Many medicines from these dichymeotherapy, for example, are made
- 13:35through these types of processes. It is not the same, but and then,
- 13:43one of the applications that developed was already in the 1950s, applying this
- 13:50technology to see if they could determine the concentrations of materials and, in this
- 13:58case, ceramics and archaeological glass. So, well, here' s a
- 14:07good person mainly who is the great driver of this application in archaeology, which
- 14:11is seir, which already in the fifties begins to do these first analyses.
- 14:18And then that' s when you realize that we can measure the elements,
- 14:26especially trace elements, those that have a very, very small composition in our
- 14:30sample and that can be characteristic of specific areas. So, knowing that there
- 14:37are areas that have compositions with characteristics of these elements, we can attribute them,
- 14:46attribute those unknown samples to those regions or to those productions or those productions.
- 14:54So, of course, as I was saying, it' s a
- 15:03very good technique at the analytical level, it' s one of the best.
- 15:05In fact, it is used to contrast other techniques, to verify that
- 15:09the other techniques are reliable. You can measure almost the entire periodic table at
- 15:16very low levels of accuracy and concentration. The only little problem he has is
- 15:24that you need a nuclear rector. So, of course I was going to
- 15:31ask you. It sounds great, but I think there' s a detail
- 15:33and it' s in the ske that I was going to comment on what
- 15:37it takes. Looks like, uh, neutron activation. Sure, sure,
- 15:41it' s the little handicap that this technique has, well, small or
- 15:46large. So, of course, of course, of course they are very
- 15:52expensive equipment, because they are nuclear reactors dedicated to research, not to electrical
- 15:56production. So, they are expensive you need, very delicate and very expensive
- 16:04equipment. Well staffed, very well trained. So, of course, because
- 16:10we don' t really have in the world, there aren' t so
- 16:15many reactors dedicated to these issues. Therefore, alternatives to neutron activation have always
- 16:18been sought. Although we know it' s the best way to chemically analyze
- 16:23a sample. There are other alternatives that are cheaper, more available, that
- 16:32are easy to buy. I don' t know in any analysis team it
- 16:37can be worth fifty hundred two hundred zero euros whatever, but of course this
- 16:44is a lot more expensive, at least to install. Then, well,
- 16:45functioning will be more or less cheap. I don' t know anymore,
- 16:51then. That is why, for example, there is one very much of
- 16:56a long tradition and a lot of prestige that is in America. There'
- 17:00s miss Es, the Missouri University Research Reactor, which is in Columbia,
- 17:06Missouri, and that' s really a benchmark in the field, in the
- 17:11field of archaeology and heritage. There are also more sites in Mexico, in
- 17:15Portugal, well, but the tendency is that there is less and less in
- 17:22respect to the need to implement other analytical techniques, of course, that result
- 17:33from much more widespread and easier access and with staff or not so much staff,
- 17:38specialized and, of course, the infrastructure of an atomic reactor that must
- 17:45be very complicated to maintain. And there is another one of these analytical techniques
- 17:52that also applies to archaeological materials and that is mass spectrometry. You could explain
- 17:59to us how, how it works and what the scopes and limits are,
- 18:03considering that you already mentioned that there are also limitations in neutron activation. Yes,
- 18:11of course, mass spectrometry or CPMS, which is mass spectrometry with inductively
- 18:18coplated plasma. That name' s been pretty long. It' s really
- 18:26a very widespread technique. I allow an elementary analysis of most of the elements
- 18:34in the periodic table to be made much cheaper than a neutron activation. Of
- 18:40course, setting up the equipment is much cheaper. Well, when I say
- 18:47much cheaper, it' s in proportion, because analytical equipment is really quite
- 18:53expensive in general. But well, then this technique really came up a little
- 19:03bit like the substitute for neutron activation. It was like that great referent from
- 19:11all over the world wants to use it, because of course it is simpler,
- 19:15cheaper to use. You don' t need a nuclear rector. That
- 19:21' s how he' s been doing the sorcery to the neutronic activation for
- 19:27years now. But it' s still not as precise or as accurate as
- 19:33the neuronic activation. The problem you have. Well, the problem is a
- 19:37matter of sample preparation especially which is a little cumbersome. You could say because
- 19:45there are various types of preparation, but they all go through. Your solid
- 19:49to liquid sample. I mean, you have to either melt or digest,
- 19:56but you have to always put it in liquid, which in the neutron,
- 20:00the electronic terration is like that reliable old car that you' ve always had
- 20:06to make noise, but you can put it in any way that it'
- 20:08s going to take you. On the other hand, the ICPM is more
- 20:12expectatometry at times, because it seems to be as delicate as it is good,
- 20:15if not under the specific conditions. Well, it gets a little worse.
- 20:22Then you have to always destroy. Your sample, of course, is
- 20:26the nectronic activation. Also that is considered a sample, a destructive technique and
- 20:33you pass from what you do is to measure your sample the passes through different
- 20:41cones, by different magnets in an entire process in which it is ionized,
- 20:48the sample becomes a plasma or is practically volatilized and you end up measuring.
- 20:56You end up separating by the mass of the different elements, different atoms or
- 21:03trillions by the detector, that is, you end up separating it and there
- 21:07you end up measuring, which is the composition, that is how much it
- 21:14shows how many ion numbers you have of a certain element that you know its
- 21:15mass. So, you can count them and measure them. Not then,
- 21:19well, it' s a pretty reliable technique and that' s why it
- 21:33' s quite successful lately very well there' s another kind of material analysis
- 21:38that I think is the one that has been most strongly positioned in recent years
- 21:45and above all by terms of portability and it' s about X- ray
- 21:49diffraction. We could explain to them how it works and, above all,
- 21:55what the advantages of this particular technique are. Yeah, here we have X
- 22:02- ray technology. There are several types of equipment. Well, it'
- 22:11s the X- rays that all of us have. That is not the
- 22:15most common thing, and it is an application of the most common and,
- 22:22fortunately, thanks to technology, because we have had it for about a hundred
- 22:26years, already or some more. So, well, that would be one.
- 22:32Then we' d have the X- ray florescence and then the X
- 22:37- ray diffraction. X- ray inflorescence is a technique used to measure the
- 22:41elementary composition of a sample. What it does is the equipment emits a sample
- 22:52as an x- ray of a specific characteristic wavelength, and what it does
- 22:57is excite the sample within that sample. Well, there' s a series
- 23:04of interactions between the atoms in the sample and what you get is basically emitting
- 23:14an energy characteristic of each element. So, with a proper detector, of
- 23:19course, what you do is okay, because I have this energy, I
- 23:23have so many accounts of this other energy, I have so many then you
- 23:30can characterize your sample elementally. Then you have, well, silicon, I
- 23:33have fifty percent aluminum, twenty- three iron, seven, etcetera. No,
- 23:40then it' s a quantitative and good and qualitative elementary technique could also
- 23:45be either. Instead, X- ray diffraction, although an X- ray
- 23:52is also used, what is physics behind that technique is different. It is
- 23:59based on that it is only possible to measure crystalline elements, that is,
- 24:03crystalline materials, for example, minerals could be crystalline material, because a crystalline
- 24:11material is that which in its molecules is ordered repeatedly in space and will always
- 24:19be so and is characteristic of that mineral or crystalline compound. It' s
- 24:26always gonna be that way. So, if you radiate with the X-
- 24:33roll and the X- ray, what it does is penetrate that crystal and
- 24:37from a certain depth, it goes through the layers of the molecules and from
- 24:45a certain depth, well, what it does is diffraction or shoots out that
- 24:51gap out at a specific angle. And that particular angle, if it fulfills
- 24:59the life of you, which is what is based on this principle, you
- 25:06can measure, then you measure, what are those angles, those differences,
- 25:11those diffraction patterns, and you have a spectrum, then spectrum. What you
- 25:18can do is compare it with international patterns that exist bookstores. And so just
- 25:26what you do is compare And you say it' s okay, because I
- 25:29have here at this point, at this point, at this point I have
- 25:33a peak, because I see which of the minerals that exist in the world
- 25:37that have been analyzed, coincide with these peaks. And then there I can
- 25:40say okay, because these three peaks match this one. So, it'
- 25:42s quartz, because whatever it is in matites. I' m not iron,
- 25:51so it' s a technique that' s very common in use.
- 25:53Really in archaeometry, it' s used, it' s used a lot
- 25:59because it has. It is qualitative, mainly, mainly a qualitative technique.
- 26:06That is, basically what we get that information of absence or presence is such
- 26:11a mineral or such compound, but it gives us a lot of information.
- 26:17It gives us a lot of information, for example, to know what kind
- 26:21of pigments we have, for example, in a ceramic or in a painting
- 26:26or in another element. Well, let' s see if that ceramic is
- 26:30painted, then in some red colors. And so, let' s see
- 26:33if it' s iron oxide, for example, or if it' s
- 26:37cinnabar, that would be its mercury fur. Sure, it changes, it
- 26:41changes a lot, and well, that then gives us reason to think,
- 26:44because if it is cinnabar, then where it comes from alcin opened in the
- 26:45area. Or there had to be a transport, there had to be an
- 26:49exchange. Everyone used cinnabar in their decorations, at home, or in their
- 26:57pots, or there is an elite that does, then, well, all
- 27:03that gives us the opportunity to talk about all these aspects. I mean,
- 27:07what we' re also trying is that it' s not just a pure
- 27:12and hard determination to have this compound, and that' s good, that
- 27:17' s what it means on an archaeological level. I think that' s
- 27:18what basically lies in the potential of archaeometry not trying to answer that. Yes,
- 27:26yes, that' s exactly what I was going to point to,
- 27:30because in the end we do get quantitative or qualitative data from elements, but
- 27:38we also need contrast information, which would be regional geology that allows us to
- 27:45contrast and know this one well. These raw materials and these characteristics are here
- 27:48me there and, of course, will come in to answer. Finally,
- 27:52what interests us is not to have a little data there and to know this
- 27:56is of such material, but that material how it gets there, it is
- 28:03local production, the raw material they brought it from the other side, is
- 28:07result of their presence of an exchange in populations, of a network of commerce.
- 28:11It is a material that is restricted to a population group, in a
- 28:17community, in a city that is directed towards archaeometry. Finally, that'
- 28:22s true, that' s totally okay. It' s that sure really
- 28:27good. This would give for a very broad debate, but not so long
- 28:33ago, what is archaeometry has been dominated mainly by chemicals, physicists, geologists
- 28:40and some with greater or lesser concern for these debates. Archaeological something more epistemological.
- 28:52Then, of course, it was quite recurrent. I believe that less
- 28:56and less and more we are in a much more truly interdisciplinary world, where
- 29:04there is a really active discussion and collaboration among all the agents who collaborate in
- 29:11an investigation. But until not so long ago, unfortunately, it wasn'
- 29:15t like that. Then it was very common to see a publication where the
- 29:22archaeologist said something, did his studies, his archaeological analyses and there was an
- 29:30appendix with archaeometric analysis, which could even go as far as to refute what
- 29:37had been said first. Then of course there was no such dialogue. Then
- 29:38it was a little bit to rub the absurd, or even less and less,
- 29:47as I say, to go to determine the identified crystalline. I don
- 29:52' t know what crystal and such and worth very well, very interesting.
- 29:57It' s a very interesting thing, but as an analytical exercise, as
- 30:03an exercise in chemistry or geology. But archaeologically, what does it mean to
- 30:07know, that ceramics such there is, I don' t know what mineral,
- 30:15which is something process has been obtained through a natural process. I don
- 30:17' t know what, I don' t know how many. All right,
- 30:18but it has some explanation to have some role in the debate. Archeological,
- 30:23we can know something clearer. That' s what we have to attack.
- 30:32Let' s just say improve on the looks of all the agents.
- 30:37Yes, there is another technique that is also frequently applied and that has to
- 30:42go with scanning electron microscopy and this technique how it works and what it serves
- 30:51us in archaeology, because this technique is one of my favorite. I really
- 30:57like it because it' s really very eye- catching. It' s
- 31:04a technique, as you say, a technique of microscopy. Therefore, it
- 31:07is an image technique, but instead of the optical micropropies, it uses light
- 31:11and lenses, between mirrors and lenses, to move the light from one place
- 31:21to another, channel it, focus it and so on and get a magnification.
- 31:26The electron microscope he uses is electrons. It emits a flow of electrons
- 31:36that interact with the sample and depend. There are several types of interaction.
- 31:41So, with that interaction in the sample, what we get is a topography
- 31:45of our sample thanks to and instead of mirrors, the electron microscope, like
- 31:55it works with electrons that are negatively charged, what it does is use magnets.
- 32:01There are more things, but as we imagine as a system of magnets
- 32:06in which in a column we manage to pass a flow of electrons and we
- 32:13can focus on our sample and obtain magnifications of the order of fifty zero magnifications.
- 32:22It really has a very great potential. In addition to obtaining large increases,
- 32:31we can go to see microscopic and even nanometric details. We can also
- 32:43like, for example, they could be I don' t know small minerals
- 32:46that tell us about a contamination, or study the clay structures of ceramics and
- 32:54then, with that, try to see if a ceramic is more or less
- 32:59cooked. Or also study pigments, for example, layers, if they have
- 33:08decoration, if they do not have, if that decoration is intentional or is
- 33:13good intentional, if there are stains and are decorations or not, if it
- 33:17has some kind of preparation, that shows if it has glazed how it is
- 33:22what characteristics. Then it allows for a very large microscopic knowledge and then,
- 33:32besides, it also allows, as you are working with electrons. In this
- 33:37interaction there are also phenomena of florescence in which you allow to characterize the sample
- 33:47chemically elementally. Then you can get to see with less precision than the other
- 33:53techniques we talked about before, the ethematries more or the nectronic activity. But
- 33:58we can come to know if our sample has a quantity of silicon, a
- 34:02quantity of aluminum, an amount of iron and good, and that also serves
- 34:07us, then, a little to characterize a pigment, for example, or
- 34:10to characterize a glaze. That could be one of the applications. For example,
- 34:19I can think of a case, which is that of majolicas from Panama,
- 34:25for example, in which, using this technique, we studied different glazed
- 34:34decorated ceramics from the old colonial period of Panama that would be up to one
- 34:40thousand six hundred seventy- one, from seventeen and then from the old town.
- 34:44And we compared whether there was any difference in these ceramics that had different
- 34:50chronologies. And indeed, with this technique we saw how they used much more
- 34:55strange in those that are older, while those that are more modern in the
- 35:00old town, because they use less strange and more inclusions in the glaze.
- 35:06And that' s the historical explanation because you were trying to get an opaque
- 35:15white glaze as opaque as possible. Then you have the traditional way is with
- 35:21tin and instead, already in the eighteenth century, well, there are also
- 35:24more difficulties to get to Panama. Really then we are all in the crisis
- 35:31of the late 17th and 18th, all the wars in which the entire Spanish
- 35:39empire embarks, with all the rest of the empires and where there really begins
- 35:46to be a shortage of some metals. So, well, we can attribute
- 35:52that technology, that technological adaptation, to that periododic, to that historical context.
- 36:00In the end, of course, we are also approaching recipes for the
- 36:07elaboration of objects that are specifically talking about technology, advances adaptations of that technology
- 36:15over time. That does, and this is a pretty, pretty interesting field
- 36:25in archaeometry. It is a little trying to understand how things were done and
- 36:34how things are changing over time, how that production, those recipes, can
- 36:39be modified according to needs or external conditioning. There may also be environmental conditioning.
- 36:47Let' s say that at some point, because you' re in
- 36:52an area where there aren' t proper clays or there' s no more
- 36:57water for whatever, or there' s water stress for whatever. Or just
- 37:02because you have less lead and less tin and then you have to look for
- 37:07life to try to make the same product as you did before, or change
- 37:13the product or make the same adaptation then there are several cases. For example,
- 37:19it occurs to me in the bask country that we did a study.
- 37:22Here there is a traditional listening production here near Vitoria, which is called in
- 37:28the Oshu in mayerías that has already been known since at least the 17th century,
- 37:35and there it was done in a traditional way. It was a glazed
- 37:39ceramic tin during the Civil War until the civil war. It remains so in
- 37:49the Spanish Civil War, which is from one thousand nine hundred thirty- six
- 37:52to thirty- nine. Well, then, for production. And when one
- 37:55of the holes is taken up, a return to production in the 1940s,
- 38:01when that resumes, because it was really scarce, there were metal shortages,
- 38:07it was a serious problem. Then he could not devote enough tin and lead
- 38:12metal to those productions. So what it does is it invents a way to
- 38:20reproduce what was done in the past, but with the shortages it had,
- 38:24with the materials it had at the time. Then, because it uses as
- 38:28an engobe or a very white layer of a very white clay, then it
- 38:32puts a very thin transparent glaze to make it look white. Well, let
- 38:37' s just say it looks a little. But good is the whole process
- 38:45of adaptation, of adaptation of resilience. It could even be called through archaeometry,
- 38:51because we could document clearly with great precision. That is, it is
- 38:55clear that all these analytical techniques that you have explained to us give us extremely
- 39:06accurate information, but there is a criticism in some cases that with the samples,
- 39:13with the groups of samples that are worked with in these techniques are usually
- 39:19limited, that is, we can not in an excavation five or six zero
- 39:22ceramic fragments can be released, cannot be analyzed all and the decision is made
- 39:29to define a sample of study in the particular case and of your experience in
- 39:36this topic, how we define that number of specimens so that it really becomes
- 39:45statistically representative. Sure, this is a big question. I think that'
- 39:52s the big question. Sure. We have to start from the beginning that
- 40:01in both narcometry and archaeology, what has come to us is a tiny part
- 40:07of what really existed. So we' re always going to be playing somehow
- 40:15with sample samples of your samples. We' re really going to have a
- 40:22very very partial vision. Now I don' t remember who said archaeology was
- 40:27like trying to make a puzzle with very few pieces you have and without having
- 40:32a picture of what the original puzzle was like. So, to me it
- 40:37has always seemed very destructive that image and really clear in archaeometry would still be
- 40:43to take a small part of how little we already have clear here. It
- 40:51depends here, it depends like a whole sampling the wider, since more representative
- 41:00it will be here. There are many studies on what percentage would be useful,
- 41:10of course, ten percent, fifteen percent, twenty percent of the total.
- 41:16The problem. The problem is, it' s gonna be expensive.
- 41:22As I said before, then the tests are quite expensive. So, of
- 41:28course you' re very limited in that respect. Not then, for example,
- 41:30if in an excavation six thousand fragments come out in a campaign, well,
- 41:36we talk about an excavation it doesn' t matter in one in a
- 41:39field, not six thousand fragments let' s say individual single fragments or minimum
- 41:45number. Not sure, 10%. It' s already six hundred fragments.
- 41:57It' s a barbarity to money that' s worth just a technique.
- 42:01If you want to use several techniques, well, I don' t
- 42:06know, because we could be easily talking about twenty or thirty zero euros.
- 42:09I don' t know. It depends, well, it depends, there
- 42:14are many factors that coincide here, but well, then clear here a strategy
- 42:20would be to try to do, above all to choose reliable contexts, that
- 42:28is to say with texts, archaeological ones, that we know that they are
- 42:36good, that we have elements to be able to date them, elements of
- 42:44consumption or use that we can really differentiate from others and make one, that
- 42:51is, for example, not to take elements superficial fragments, because that is
- 42:53often what happens many times, that is good, since they are going to
- 42:57be destroyed, because well give them those cacheros that not that totally caught them
- 42:59here next to, that I don' t know even what they are.
- 43:00Not sure, that' s not worth anything. It won' t do
- 43:02me any good, and neither will you. I' m not gonna be
- 43:05able to give you an answer to what you might ask yourself. So we
- 43:10have to try, between the archaeologist and the archaeologist to see what are the
- 43:19questions to answer and what can be analyzed and with what techniques, that is,
- 43:25what can be destroyed and what cannot be destroyed. So, there'
- 43:32s some percentage here. Not before they do random sampling studies, for example,
- 43:42for everyone we have a bias and then of course that the one doing
- 43:47the sampling, because it also has a bias It is best that he is
- 43:52interested, because certain typologies, or he likes them more then, well,
- 43:55he gets more into that bag of analysis, or he wants to do a
- 44:05type of studies, because I don' t know. Maybe he' s
- 44:06more interested in colonial pottery than the local one. I don' t know,
- 44:10then, well. It' s really a very difficult question to answer.
- 44:16It is very difficult to respond, that is, how many samples would
- 44:21be needed, because the better, that would be the answer. That'
- 44:24s the best answer. And orbe is also aimed at the questions that one
- 44:29has in research, to the knowledge that one has in the collection. Surely
- 44:34if one knows and well you put the case of the Panamanian mayolics, if
- 44:37one knows them well their typologies, then surely it does not have to know.
- 44:43In addition, because some previous studies have already been done, which are
- 44:47already defined as recipes by potters. Then one can delve into some questions and
- 44:55surely also limit the number of copies to be analyzed and, in addition,
- 45:02decide what kind of analytical technique to use the one that fits improves to solve
- 45:07that question. An issue that I think is important to mention now that we
- 45:14are talking about, and it has to do with those colleagues who are starting
- 45:20to work on archaeology, who are eager to do archaeometric studies and, at
- 45:25times, because this is like a shot into the air, they start to
- 45:34wrongly explore what would you suggest to start an archaeometric study of an archaeological collection?
- 45:40What criteria should that colleague take into account before saying here is it worth
- 45:46doing an archaeometric study? Sure. This question is quite recurring, not clear
- 45:57and the answer, well, whenever he tried to answer it. My head
- 46:04' s coming. The song of being famous and great singer, which was
- 46:08pau ones and the group stick syrup. I don' t know if you
- 46:14know him anymore. They had a very good song, very nice, plus
- 46:19it was titled. Depends. That' s right, it really depends.
- 46:24There are many factors that play in this game. For example, we would
- 46:34first have to see what material we have at our disposal. No. If
- 46:37it' s a ceramic, it' s one thing, if it'
- 46:40s a metal, it' s another, if it' s a glass,
- 46:42is it another? If it is something organic, then it will have
- 46:46other things then also good, because there is mainly to see which questions we
- 46:52want to answer. That' s the first thing. First, first you
- 46:54have to ask yourself what I want to know, because it is not the
- 47:00same to know age, to know the origin, to know the technology,
- 47:07to know if it is authentic, for example, could be another question,
- 47:13whether it is something authentic or not the function of that piece. What function
- 47:15it could have, since we can aim with archaeological studies, but with archaeometric
- 47:21studies. Maybe it also depends on whether there is any residue or any rest
- 47:23that we can analyze, because all these are questions that need to be assessed
- 47:34before making any decisions. I mean, what do I want to answer if
- 47:38I want to know the source, that is, where each piece comes from
- 47:43to do an exchange or trade study, because that' s going to lead
- 47:47us to a number of techniques. So, or if I want technology,
- 47:52it' s going to lead us to another one, that is, it
- 47:53' s coming, because maybe what we' re trying to do is a
- 47:57chemical analysis. It could be a petographic analysis, which we talked about,
- 48:00but well, there' s also more techniques. So, of course,
- 48:04a chemical allasis, for example, because or I can be, as we
- 48:07said, ICP, neutron activation, X- radii fluorescence. Well, there
- 48:12are several. If we want an analysis, solve a technological question, how
- 48:21was that piece made, not what is it made of? It has glaze
- 48:25that glaze is of lead plomonos which type of material composes it. Well,
- 48:31that would all be another kind of other techniques requiring it It could be,
- 48:37for example, electronic microscopy, for example, it would be a good technique
- 48:45to try to explore those questions. And then the other big question, the
- 48:51other big question that needs to be assessed is worth it very well, I
- 48:58want to know this and for that I have to use this technique. Okay.
- 49:01You can either destroy the piece or you can' t destroy it.
- 49:06I think that' s the basis of any study. There are techniques that
- 49:13are destructive by nature, as we have seen, such as neutron activation or
- 49:17mass spectrometry and others that may or may not be, such as X-
- 49:22ray florescence, diffraction or electron microscope may not be destructive. Then, there
- 49:29you have to value. I have enough samples. Yeah, they' re
- 49:35significant. Then I can do a destructive analysis. Perfect. I can'
- 49:40t do a descriptive ansis, because I only have one sample call is complete
- 49:45and it' s in a showcase at the museum. There with lights and
- 49:47posters. Of course, perhaps we cannot benefit from that destructive analysis, not
- 49:54compensate to destroy that piece that is perhaps one in the region. I don
- 50:00' t know. So, all these issues are important to value. And
- 50:07then one that you often don' t forget, but I don' t
- 50:14know where you should put it in that whole scheme is how much it costs,
- 50:22because it really seems like it' s a little thing. But tests
- 50:23like I said are expensive, they' re usually expensive. So, well,
- 50:29the important thing or my Council, at least for all listeners, would
- 50:34be to try to collaborate with institutions that do these analyses and tempt against funding.
- 50:42Obviously not, but good. We often know it' s complicated,
- 50:46but collaborating can open many doors, because it' s not just ordering an
- 50:52analysis. It takes my sample to analyze it. We are not going to
- 50:55ask a joint project, we are going to see what questions we can answer
- 51:00and from that dialogue, which is very enriching for both parties, a project
- 51:06or a less analytical strategy will emerge, it is much more robust, with
- 51:13much more solid results, which will surely bring much more to the Community.
- 51:17Clear from a discussion between the questions and who is fit and who can do
- 51:24the analyses. The technique, the number of copies and, of course,
- 51:31the budgetary resources required to carry these studies forward will surely be precise. Finally,
- 51:40Javier, in conclusion, I want to ask you how science and technology
- 51:46are now moving forward in a very fast way, what are the big questions
- 51:53that are now coming to archaeometry and that will seek to resolve in the near
- 52:00future where geometry will be directed in the near future. I believe that this
- 52:07is my opinion, my opinion based on my experience and the congresses I have
- 52:14attended lately and the publications that you see are increasingly being published. I believe
- 52:21that at least one of the great fields to which archaeometry is directed is really
- 52:27towards non- destructive analysis. I think it' s not only one of
- 52:32the big fields, but it' s one of the most necessary fields.
- 52:37From what we were saying, there are no materials that cannot necessarily be destroyed.
- 52:45Like it or not we might say if we could analyze, I don
- 52:47' t know what' s already clear, but it' s just that
- 52:52it' s unique is that that piece actually has a museum value in itself,
- 52:58has an intrinsic value or even has a cultural value for a population group.
- 53:02Then it cannot be destroyed, but perhaps non- destructive techniques could be
- 53:08used. So that' s where you' re going to archeometry recently,
- 53:14in the last ten years, a lot of equipment has been developed, not
- 53:20only non- destructive, but also portable. So more and more you see
- 53:27even the own excavations, going with a portable equipment, analyzing, insitu the
- 53:32material that you have just excavated or even with chemical analyzers of florescence of radios
- 53:38x portable, analyzing, for example, soil a stratum, trying an area,
- 53:45trying to see if there is any marker that tells us if one more
- 53:52area of habitat or a bonfire or an industrial zone, then do as a
- 53:57kind of chemical prospecting. That' s getting more and more common and we
- 54:04' re going there. Of course we could also talk that if genetic,
- 54:07that if good bioarchaeology as if not. In my field, I can'
- 54:13t talk much about not being able to expand on that either. But what
- 54:15is inorganic materials. The non- destructive anthesis is definitely going to revolutionize.
- 54:22Or it' s already revolutionizing, because it' s really already revolutionizing what
- 54:27is the field of archaeometry here not so many years. I don' t
- 54:31know how we treat ourselves archaeologically. I predict that destructive analyses will become more
- 54:39and more residual, that is, in fact, increasingly tend to make non
- 54:45- destructive assis and they will be more precise, more accurate and truly we
- 54:52will all benefit. I think it' s going that way, the field,
- 54:55it' s going inexorably that way. Javier, thank you so much
- 55:01for your time, for your generosity and for sharing your experience. It has
- 55:06been as always a taste, although there has been no beer to talk to
- 55:12you and good we will continue to produce scientific content in this podcast, the
- 55:15future Neck. Thank you very much. It has been a pleasure for me
- 55:21to be with you and discuss these very interesting issues. Thank you very much
- 55:24for my herma.